/sbin/ifconfig
and read off the "ether" value for en0.
For example:
$ /sbin/ifconfig lo0: flags=8049The MAC Address is: 00:16:cb:cd:3b:4dmtu 16384 inet6 ::1 prefixlen 128 inet6 fe80::1%lo0 prefixlen 64 scopeid 0x1 inet 127.0.0.1 netmask 0xff000000 gif0: flags=8010 mtu 1280 stf0: flags=0<> mtu 1280 en0: flags=8863 mtu 1500 inet6 fe80::216:cbff:fecd:3b4d%en0 prefixlen 64 scopeid 0x4 inet 172.17.102.238 netmask 0xffff0000 broadcast 172.17.255.255 ether 00:16:cb:cd:3b:4d media: autoselect (100baseTX ) status: active supported media: autoselect 10baseT/UTP 10baseT/UTP 10baseT/UTP 10baseT/UTP 100baseTX 100baseTX 100baseTX 100baseTX 1000baseT 1000baseT 1000baseT none en1: flags=8863 mtu 1500 ether 00:16:cb:bc:cb:0a media: autoselect ( ) status: inactive supported media: autoselect wlt1: flags=41 mtu 1500 fw0: flags=8863 mtu 2030 lladdr 00:16:cb:ff:fe:de:8e:7a media: autoselect status: inactive supported media: autoselect